1402076-72-5

Basic information

• Product Name: (E)-N-(6-(benzyloxy)hexa-1,3-dien-2-yl)-N-methylacetamide
• Synonyms: (E)-N-(6-(benzyloxy)hexa-1,3-dien-2-yl)-N-methylacetamide
• CAS NO: 1402076-72-5
• Molecular Weight: 259.348
• Mol File: 1402076-72-5.mol

Chemical Properties

• CAS DataBase Reference: (E)-N-(6-(benzyloxy)hexa-1,3-dien-2-yl)-N-methylacetamide(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N-(6-(benzyloxy)hexa-1,3-dien-2-yl)-N-methylacetamide(1402076-72-5)
• EPA Substance Registry System: (E)-N-(6-(benzyloxy)hexa-1,3-dien-2-yl)-N-methylacetamide(1402076-72-5)

Safety Data

• Hazardous Substances Data: 1402076-72-5(Hazardous Substances Data)

Upstream product

• 3195-78-6 N-vinyl-N-methylacetamide 
• 185453-07-0 (E)-4-(benzyloxy)but-1-enylboronic acid 

Relevant articles and documents

Catalyst-controlled regioselectivity in the synthesis of branched conjugated dienes via aerobic oxidative heck reactions

Pd-catalyzed aerobic oxidative coupling of vinylboronic acids and electronically unbiased alkyl olefins provides regioselective access to 1,3-disubstituted conjugated dienes. Catalyst-controlled regioselectivity is achieved by using 2,9-dimethylphenanthroline as a ligand. The observed regioselectivity is opposite to that observed from a traditional (nonoxidative) Heck reaction between a vinyl bromide and an alkene. DFT computational studies reveal that steric effects of the 2,9-dimethylphenanthroline ligand promote C-C bond formation at the internal position of the alkene.