1402248-96-7Relevant academic research and scientific papers
Crystal structure of BIS[2-((E)-(p-tolylimino) methyl)-6-bromo-4- chlorophenol]copper(II)
Pu, X. H.
, p. 603 - 605,3 (2012)
A new complex CuL2 1 [HL = 2-((E)-(p-tolylimino) methyl)-6-bromo-4-chlorophenol] is obtained and characterized using the single crystal X-ray diffraction analysis. The crystal belongs to the monoclinic system, P21/c space group, with a = 13.3203(13) A, b = 12.3052(11) A, c = 17.8664(17) A, β = 105.3420(10)°, V = 2824.1(5) A3, Z = 4, Dc = 1.672 g/cm3, R1 = 0.0686. The geometry around copper(II) is intermediate between square planar and tetrahedral. The units of the complex are linked via weak intermolecular Br...Br contracts, leading to the formation of one-dimension (1D) chains along the b axis; the multipoint Cu...Cl intermolecular interactions extend the 1D chain into a 2D layer. Original Russian Text Copyright
