1402349-71-6Relevant articles and documents
Enantioselective synthesis of tertiary α-hydroxy phosphonates catalyzed by carbohydrate/cinchona alkaloid thiourea organocatalysts
Kong, Shasha,Fan, Weidong,Wu, Guiping,Miao, Zhiwei
, p. 8864 - 8867 (2012/10/08)
A pinch of sugar: The new bifunctional carbohydrate/cinchonine-based thiourea 1 has been designed for the asymmetric addition reaction of α-ketophosphonates and trimethylsilyl cyanide, the product of which can be hydrolyzed to afford tertiary α-hydroxy phosphonates with excellent enantioselectivities. Copyright