14024-17-0

Basic information

• Product Name: Ferrous acetylacetonate
• Synonyms: (Acetylacetonato)iron;(Acetylacetonato)iron (ii);bis(1,4-Pentanedionato) iron;Bis(2,4-pentanedionato)iron;bis(2,4-pentanedionato-O,O’)-Iron;Bis(acetylacetonato)iron;Ferroacetylacetonate;Iron bis(acetylacetonate)
• CAS NO: 14024-17-0
• Molecular Formula: C10H14FeO4
• Molecular Weight: 254.06
• EINECS: 237-851-4
• Mol File: 14024-17-0.mol
• Article Data: 0

Chemical Properties

• Melting Point: 175 °C (dec.)(lit.)
• Boiling Point: 187.6oC at 760 mmHg
• Flash Point: 71.9oC
• Appearance: dark brown powder
• Storage Temp.: Inert atmosphere,Room Temperature
• CAS DataBase Reference: Ferrous acetylacetonate(CAS DataBase Reference)
• NIST Chemistry Reference: Ferrous acetylacetonate(14024-17-0)
• EPA Substance Registry System: Ferrous acetylacetonate(14024-17-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 14024-17-0(Hazardous Substances Data)

Usage

Chemical Properties

dark brown powder

Synthetic route

iron(acetylacetonate)2 (14024-17-0) + 2Li(1+)*{(C5H3)Si2(CH3)4Si2(CH3)4(C5H3)}(2-) = Li2{(C5H3)Si2(CH3)4Si2(CH3)4(C5H3)} + pentamethylcyclopentadienyllithium (51905-34-1) → ((C5H3)Si2(CH3)4Si2(CH3)4(C5H3))Fe (135043-07-1)

Conditions	Yield
In tetrahydrofuran byproducts: Li(acac), LiC5Me5; to a solution of Fe(acac)2 was added a suspension of C5Me5Li at -80°C; stirring for 30 min at -60°C; warmed at 0°C; the Si-compound was added at -70°C; warmed; stirring 1 h at room temperature; evaporated in vacuo; residue was treated with hexane; solution was evaporated; crystallization at -20°C; elem. anal.;	40%