1402429-80-4Relevant articles and documents
Unique photochemical behavior of novel tetracationic pyrene derivative on the clay surface
Hagiwara, Satomi,Ishida, Yohei,Masui, Dai,Shimada, Tetsuya,Takagi, Shinsuke
, p. 5800 - 5802 (2012)
Novel tetracationic pyrene derivative (1,3,6,8-tetrakis(N-methylpyridinium- 4-yl)pyrene, Py4+) was synthesized. Photochemical properties such as fluorescence quantum yield and fluorescence lifetime were observed for Py 4+ and Py
Organic monomer 1, 3, 6, 8-tetrapyridylpyrene and synthetic method thereof
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Paragraph 0020-0030, (2021/04/14)
The invention discloses an organic monomer 1, 3, 6, 8-tetrapyridylpyrene and a synthetic method thereof. The molecular formula of the organic monomer is C36N4H22, and the organic monomer is a fused ring compound which is formed by respectively connecting four pyridines to positions 1, 3, 6 and 8 by taking a pyrene ring as a center. The method comprises the following steps: in an argon atmosphere, adding 4-pyridylboronic acid, 1, 3, 6, 8-tetrabromo pyrene and potassium carbonate into a mixed solvent of dioxane and water, adding palladium chloride and tetrakis (triphenylphosphine) palladium to catalyze the system to catalyze the reaction system, and carrying out solvothermal recrystallization on the crude product to obtain the crystalline product 1, 3, 6, 8-tetrapyridylpyrene. The organic monomer obtained in the invention has high crystallinity, so that the accurate structure of the compound is characterized by an X-monocrystalline diffraction instrument, the original powder diffraction peak is simulated, the synthesis method is simple, the product is easy to separate and characterize, the light absorption range can reach the visible light region, the method has potential application value in the aspects of synthesis of functional materials and photoelectrocatalysis.