1402544-07-3Relevant academic research and scientific papers
Development of a Storable Triazinone-Based Reagent for O- p-Methoxybenzylation under Mild Heating Conditions
Fujita, Hikaru,Terasaki, Hiromitsu,Kakuyama, Satoshi,Hioki, Kazuhito,Kunishima, Munetaka
supporting information, (2019/05/08)
A new triazinone-based reagent for O-p-methoxybenzylation has been developed. In spite of its stability in solid form, this reagent converts a free alcohol into the corresponding p-methoxybenzyl ether with mild heating (50-60 °C) in a solution. High funct
A practical method for p -methoxybenzylation of hydroxy groups using 2,4,6-tris(p -methoxybenzyloxy)-1,3,5-triazine (TriBOT-PM)
Yamada, Kohei,Fujita, Hikaru,Kitamura, Masanori,Kunishima, Munetaka
, p. 2989 - 2997 (2013/11/06)
A new acid-catalyzed p-methoxybenzylating reagent, 2,4,6-tris(p- methoxybenzyloxy)-1,3,5-triazine (TriBOT-PM), has been developed. The reaction of acid- and alkali-labile alcohols with TriBOT-PM in the presence of a catalytic amount of various acids (TfOH, BF3·OEt2, CSA, etc.) afforded the corresponding p-methoxybenzyl ethers in good yields. Since TriBOT-PM is an air-stable crystalline solid and can be prepared from inexpensive materials, i.e. cyanuric chloride and anisyl alcohol, this route is of practical use. Georg Thieme Verlag Stuttgart, New York.
A mild and versatile method for the synthesis of alkyl ethers from methoxymethyl ethers and application to the preparation of sterically crowded ethers
Minamitsuji, Yutaka,Kawaguchi, Atsuhisa,Kubo, Ozora,Ueyama, Yoshifumi,Maegawa, Tomohiro,Fujioka, Hiromichi
supporting information; experimental part, p. 1861 - 1866 (2012/09/22)
A mild and divergent route for the synthesis of alkyl ethers from methoxymethyl (MOM) and methoxyethyl (ME) ether derivatives via pyridinium-type salt intermediates has been developed. The addition of organocuprates to the salts afforded the corresponding alkyl ethers, including highly crowded ones, in high yields even in the presence of acid- or base-sensitive functional groups. Copyright
