1402604-67-4Relevant academic research and scientific papers
Ru-Catalyzed Redox-Neutral Cleavage of the N-O Bond in Isoxazolidines: Isatogens to Pseudoindoxyls via a One-Pot [3 + 2]-Cycloaddition/N-O Cleavage
Suneel Kumar, Chepuri V.,Ramana, Chepuri V.
supporting information, p. 2870 - 2873 (2015/06/30)
A novel metal-catalyzed oxygen atom transfer reaction onto olefins is reported. By taking isatogens as substrates, a one-pot [3 + 2]-cycloaddition of nitrone with olefins followed by the Ru-catalyzed redox-neutral N-O bond cleavage of intermediate isoxazo
Exploration of forbidden povarov processes as a source of unexpected reactivity: A multicomponent Mannich-Ritter transformation
Preciado, Sara,Vicente-García, Esther,Llabrés, Salomé,Luque, F. Javier,Lavilla, Rodolfo
supporting information; experimental part, p. 6874 - 6877 (2012/10/08)
When a door closes, a window opens! The use of geometrically or electronically restricted imines for Povarov-type processes does not afford the anti-Bredt tetrahydroquinolines, but leads instead to highly functionalized structures through novel reaction pathways (see picture; LA=Lewis acid). The exploration of forbidden routes constitutes a valuable approach in the search for new multicomponent reactions. Copyright
