1402604-68-5Relevant articles and documents
Exploration of forbidden povarov processes as a source of unexpected reactivity: A multicomponent Mannich-Ritter transformation
Preciado, Sara,Vicente-García, Esther,Llabrés, Salomé,Luque, F. Javier,Lavilla, Rodolfo
supporting information; experimental part, p. 6874 - 6877 (2012/10/08)
When a door closes, a window opens! The use of geometrically or electronically restricted imines for Povarov-type processes does not afford the anti-Bredt tetrahydroquinolines, but leads instead to highly functionalized structures through novel reaction pathways (see picture; LA=Lewis acid). The exploration of forbidden routes constitutes a valuable approach in the search for new multicomponent reactions. Copyright
