1402748-61-1

Basic information

• Product Name: (1,1,1-trifluoro-5-phenyl-2-pentylsulfonyl)benzene
• Synonyms: (1,1,1-trifluoro-5-phenyl-2-pentylsulfonyl)benzene
• CAS NO: 1402748-61-1
• Molecular Weight: 342.382
• Mol File: 1402748-61-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1,1,1-trifluoro-5-phenyl-2-pentylsulfonyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (1,1,1-trifluoro-5-phenyl-2-pentylsulfonyl)benzene(1402748-61-1)
• EPA Substance Registry System: (1,1,1-trifluoro-5-phenyl-2-pentylsulfonyl)benzene(1402748-61-1)

Safety Data

• Hazardous Substances Data: 1402748-61-1(Hazardous Substances Data)

Upstream product

• 56354-44-0 β,β,β-trifluoroethyl phenyl sulfone 
• 86537-61-3 ethyl cinnamylcarbonate 

Downstream Products

• 1402748-76-8 (4-trifluoromethyl-1-phenylhept-6-ene-4-ylsulfonyl)benzene 

Relevant articles and documents

Decarboxylative allylation of trifluoroethyl sulfones and approach to difluoromethyl compounds

Allyl carbonates undergo palladium-catalyzed decarboxylative allylation of trifluoroethyl phenyl sulfones. The success of the allylation, which is not efficient under typical strong base-mediated conditions, is the result of mild conditions thanks to a progressive delivery of ethoxide. Indeed, ethyl allyl carbonates act as a latent source of ethoxide for generation of the trifluoroethyl carbanion that reacts with the π-allylpalladium complex. The utility of the method is illustrated in a new approach to difluoromethyl compounds.