1402750-99-5Relevant articles and documents
C-H activation in S-alkenyl sulfoximines: An endo 1,5-hydrogen migration
Gao, Xuefeng,Gaddam, Vikram,Altenhofer, Erich,Tata, Rama Rao,Cai, Zhengxin,Yongpruksa, Nattawut,Garimallaprabhakaran, Aswin K.,Harmata, Michael
, p. 7016 - 7019 (2012)
Intramolecular redox reaction: Heating N-alkyl, N-allyl-, and N-benzyl-substituted S-alkenyl sulfoximines under appropriate conditions results in the formation of NH-S-alkyl sulfoximines. The intramolecular redox reaction involves a hydride transfer that occurs by a 6-endo-trig process. The intermediates in the reaction can also give access to four- and six-membered heterocyclic rings and a new class of chiral dienes. Copyright