1403327-83-2Relevant academic research and scientific papers
Rhodium-catalyzed ring opening of benzocyclobutenols with site-selectivity complementary to thermal ring opening
Ishida, Naoki,Sawano, Shota,Masuda, Yusuke,Murakami, Masahiro
supporting information, p. 17502 - 17504,3 (2020/09/16)
A rhodium catalyst induced ring opening of benzocyclobutenols with selective cleavage of the C(sp2)-C(sp3) bond adjacent to the hydroxyl group. The site-selectivity markedly contrasted with that of their thermal ring-opening reaction. The rhodium-catalyzed ring opening led to the development of a new alkyne insertion reaction constructing a dihydronaphthalene framework.
