1403486-35-0Relevant academic research and scientific papers
Microwave-assisted palladium-catalyzed allylation of β-enaminones
Erray, Imen,Rezgui, Farhat,Oble, Julie,Poli, Giovanni
, p. 2196 - 2200 (2014)
A new palladium-catalyzed approach for the C-allylation of β-enaminones under microwave irradiation is reported. This methodology provides an easy access to a variety of α-allylated enaminones. The reaction takes place with the preservation of the enamine function, which is poised for further transformations towards nitrogen-containing heterocycles. Georg Thieme Verlag Stuttgart New York.
Synthesis of enaminones by rhodium-catalyzed denitrogenative rearrangement of 1-(N -Sulfonyl-1,2,3-triazol-4-yl)alkanols
Miura, Tomoya,Funakoshi, Yuuta,Morimoto, Masao,Biyajima, Tsuneaki,Murakami, Masahiro
supporting information, p. 17440 - 17443,4 (2012/12/12)
Enaminones are synthesized by the rhodium(II)-catalyzed denitrogenative rearrangement reaction of 1-(N-sulfonyl-1,2,3-triazol-4-yl)alkanols, which are readily prepared from propargylic alcohols and N-sulfonyl azides. Intramolecular 1,2-hydride (or -alkyl)
