1403494-89-2Relevant academic research and scientific papers
Palladium-mediated phosphine-dependent chemoselective bisallylic alkylation leading to spirocarbocycles
Clavier, Hervé,Giordano, Laurent,Tenaglia, Alphonse
supporting information; experimental part, p. 8648 - 8651 (2012/09/22)
Cycles everywhere: The selectivity in the transformations of 1,3-diones to carbocycles by palladium-catalyzed bisallylic alkylations is strongly dependent on the phosphine that is employed (see scheme). Moreover, synthesized vinylcyclopentenes can be easily transformed into cycloheptadiene derivatives through a carboncarbon allylic bond cleavage.
