1403763-45-0Relevant academic research and scientific papers
Copper(II) and cadmium(II) complexes based on N,N-Bis(3, 5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine ligand: Syntheses, structures, magnetic, and luminescent properties
Yang, Lijuan,Chen, Wenqian,Chen, Yanmei,Liu, Wei,Lei, Tao,Li, Lei,Lin, Miaoshui,Wu, Jian,Cao, Yanyuan,Li, Wu,Li, Yahong
, p. 1833 - 1838 (2012)
The reaction of the aryl-oxide ligand H2L [H2L = N,N-bis(3, 5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine] with CuSO 4·5H2O, CuCl2·2H2O, CuBr2, CdCl2·2.5H2O, and Cd(OAc) 2·2H2O, respectively, under hydrothermal conditions gave the complexes [Cu(H2L1)2]·SO 4·3CH3OH (1), [Cu2(H2L 2)2Cl4] (2), [Cu2(H 2L2)2Br4] (3), [Cd 2(HL)2Cl2] (4), and [Cd2(L) 2(CH3COOH)2]·H2L (5), where H2L1 [H2L1 = 2, 4-dimethyl-6- ((pyridin-2-ylmethylamino)methyl)phenol] and H2L2 [H 2L2 = 2-(2, 4-dimethyl-6-((pyridin-2-ylmethylamino)methyl) phenoxy)-4, 6-dimethylphenol] were derived from the solvothermal in situ metal/ligand reactions. These complexes were characterized by IR spectroscopy, elementary analysis, and X-ray diffraction. A low-temperature magnetic susceptibility measurement for the solid sample of 2 revealed antiferromagnetic interactions between two central copper(II) atoms. The emission property studies for complexes 4 and 5 indicated strong luminescence emission. Copyright
