1403879-24-2Relevant articles and documents
Stabilization of an intramolecularly coordinated stannylidenium cation
Martincova, Jana,Dostal, Libor,Ruzicka, Ales,Jambor, Roman,Herres-Pawlis, Sonja
, p. 1672 - 1675,4 (2012)
The treatment of trans-{[2, 6-(Me2NCH2) 2C6H3]SnI}2PtI2 with Na(pyt) (pyt = 2-mercaptopyridine) yielded the unprecedented complex {{[2, 6-(Me2NCH2)2C6H3]Sn} Pt(μ-pyt)2I} (1), where a Sn←N coordinated stannylidenium (LSnII)+ fragment donates a to a [PtII(pyt) 2I]- anion. Compound 1 was characterized by NMR spectroscopy and molecular structure was determined by X-ray diffraction analysis. The bonding situation in 1 was analyzed by DFT studies. Copyright