140404-36-0Relevant academic research and scientific papers
Chiral Trifluoromethylated 2-Butenolides for the Construction of 6-Deoxy-6,6,6-trifluorosugars
Yamazaki, Takashi,Mizutani, Kenji,Takeda, Mitsunori,Kitazume, Tomoya
, p. 55 - 57 (2007/10/02)
Optically active 2-butenolides with a trifluoromethyl (CF3) group are synthesized via enzymatic optical resolution and are selectively transformed into 6,6,6-trifluororhodinose and amicetose by base-promoted 1,2-migration of a tert-butyldimethylsilyl moiety in a highly efficient manner.
