140407-84-7Relevant academic research and scientific papers
The Acid-Catalyzed Cyclization of Unsaturated Carbonyl Compounds Utilizing Silica Gel at High Pressure
Dauben, William G.,Hendricks, Robert T.
, p. 603 - 606 (1992)
The ene-like cyclizations of a series of unsaturated carbonyl compounds have been studied using silica gel at high pressure (15 kbar) as a new catalytic system.This new method is general for forming 5- and 6-membered ring carbocycles.The mildness of this
Stereoselective Synthesis of Alcohols, XLIII. Asymmetric Induction on the Intramolecular Allylboration Reaction of (8-Oxo-2-octenyl)boronates
Hoffmann, Reinhard W.,Sander, Thomas
, p. 1185 - 1192 (2007/10/02)
The cyclization of (8-oxo-2-octenyl)boronates having methyl substituents in the chain linking the two functional groups proceeds with complete simple diastereoselectivity and with induced diastereoselectivity of 85 to >98percent to give methyl-substituted 2-vinylcyclohexanols. - Key Words: Cyclization, stereoselective / Allylboration, intramolecular / Boronates
