1404100-36-2Relevant academic research and scientific papers
Gold-catalyzed functionalization of unactivated C(sp3)-H bonds by hydride transfer facilitated by alkynylspirocyclopropanes
Barluenga, Jose,Sigueeiro, Rita,Vicente, Ruben,Ballesteros, Alfredo,Tomas, Miguel,Rodriguez, Miguel A.
supporting information, p. 10377 - 10381 (2012/11/13)
A Golden Gate: Alkynylspirocyclopropanes served as a template for the development of gold-catalyzed hydride transfer from unactivated C(sp 3)-H bonds to electronically neutral alkynes. A variety of interesting carbocyclic structures can be accessed selectively with the appropriate choice of the reaction conditions. Mechanistic studies support a sequential gold-catalyzed cleavage of C-H and C-C bonds. Copyright
