1404225-02-0Relevant articles and documents
Rhodium-catalyzed enantioselective vinylogous addition of enol ethers to vinyldiazoacetates
Smith, Austin G.,Davies, Huw M. L.
supporting information, p. 18241 - 18244 (2013/01/15)
A highly asymmetric vinylogous addition of acyclic silyl enol ethers to siloxyvinyldiazoacetate is described. The reaction features a diastereoselective 1,4-siloxy group migration event. Products are obtained in up to 97% ee. When more sterically crowded