1404232-85-4Relevant academic research and scientific papers
Supramolecular frameworks of binuclear dioxomolybdenum(vi) complexes with ONS donor ligands using 4,4′-azopyridine as a pillar: crystal structure, DFT calculations and biological study
Biswal, Debanjana,Pramanik, Nikhil Ranjan,Chakrabarti, Syamal,Drew, Michael G. B.,Mitra, Payel,Acharya, Krishnendu,Biswas, Sujan,Mondal, Tapan Kumar
, p. 8681 - 8694 (2015)
Three new isostructural pillared binuclear dioxomolybdenum(vi) complexes [(MoO2L1)2(4,4′-azpy)] (1), [(MoO2L2)2(4,4′-azpy)] (2) and [(MoO2L3)2(4,4′-azpy)] (
Synthesis, structural characterization and electrochemical studies of nickel(II), copper(II) and cobalt(III) complexes of some ONS donor ligands derived from thiosemicarbazide and S-alkyl/aryl dithiocarbazates
Ali, Mohammad Akbar,Tan, Ai Ling,Mirza, Aminul Huq,Santos, Jose H.,Abdullah, Aimi Hanisah Bte Hj
, p. 651 - 659 (2012)
Four tridentate ONS ligands, namely 2-hydroxyacetophenonethiosemicarbazone (H2L1), the 2-hydroxyacetophenone Schiff base of S-methyldithiocarbazate (H2L2), the 2-hydroxy-5-nitrobenzaldehyde Schiff base of S-methyldithiocarbazate (H2L3), and the 2-hydroxy-5- nitrobenzaldehyde Schiff base of S-benzyldithiocarbazate (H2L4), and their complexes of general formula [Ni(HL1)], [ML] (M = NiII or CuII; L = L1, L2, L3 and L4), [Co(HL)(L); L = L1, L2, L3 and L4] and [ML(B)] (M = NiII or CuII; L = L2 and L 4; B = py, PPh3) have been prepared and characterized by physico-chemical techniques. Spectroscopic evidence indicates that the Schiff bases behave as ONS tridentate chelating agents. X-ray crystallographic structure determination of [NiL2(PPh3)] and [CuL 4(py)] indicates that these complexes have an approximately square-planar structure with the Schiff bases acting as dinegatively charged ONS tridentate ligands coordinating via the phenoxide oxygen, azomethine nitrogen and thiolate sulfur atoms. The electrochemical properties of the complexes have been studied by cyclic voltammetry. Springer Science+Business Media B.V. 2012.
