1404273-50-2Relevant academic research and scientific papers
SPANphos ligands in palladium-catalyzed asymmetric fluorination
Jacquet, Olivier,Clement, Nicolas D.,Blanco, Carolina,Belmonte, Marta Martinez,Benet-Buchholz, Jordi,Van Leeuwen, Piet W. N. M.
experimental part, p. 4844 - 4852 (2012/10/18)
The synthesis of new enantiopure wide-bite-angle diphosphanes is described as well as their use in the palladium-catalyzed asymmetric fluorination of α-cyanoacetates. Enantiomeric excesses up to 93 % were obtained when Pd(OAc)2-SPANphos was use
