140438-35-3Relevant academic research and scientific papers
Crystal structures and 29Si NMR calculations of amino-functionalized silyllithium compounds
Strohmann, Carsten,Ulbrich, Oliver,Auer, Dominik
, p. 1013 - 1018 (2001)
X-ray structural analysis of the amino-functionalized silyllithium compounds tris(tetrahydrofuran)[bis(diethylamino)phenylsilyl]lithium (4·3THF) and tris(tetrahydrofuran)[(diethylamino)bisphenylsilyl]lithium (7·3THF) are presented. Both compounds are mono
Synthetic applications of functionalized silyl anions: Aminosilyl anions as hydroxy anion equivalent
Tamao, Kohei,Kawachi, Atsushi,Tanaka, Yoko,Ohtani, Hitoshi,Ito, Yoshihiko
, p. 5765 - 5772 (2007/10/03)
An (aminosilyl)lithium and the corresponding copper and magnesium reagents serve as a hydroxy anion equivalent through (1) allylic substitution, (2) addition to vinyloxirane, and (3) addition to acetylene, followed by oxidative cleavage of the silicon-carbon bonds. Highly regio- and stereoselective transformations have been achieved in all cases.
