1404479-60-2Relevant articles and documents
Rhodium(iii)-catalyzed allylic C-H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines
Cochet, Thomas,Bellosta, Veronique,Roche, Didier,Ortholand, Jean-Yves,Greiner, Alfred,Cossy, Janine
supporting information, p. 10745 - 10747 (2013/01/15)
For the first time, intramolecular allylic amination was conducted using rhodium(iii) according to an "inner-sphere" type mechanism with amines activated by only one electron-withdrawing group. The activation of C(sp 3)-H bonds was chemoselective and allows the access to a variety of substituted cyclic amines such as pyrrolidines and piperidines.