140458-08-8Relevant academic research and scientific papers
ANOMALOUS IODINATION AND IODOCHLORINATION OF 3,4-DIMETHYL-CIS-BICYCLONONA-3,7-DIENE
Andreev, V. A.,Pekhk, T. I.,Anfilogova, S. N.,Belikova, N. A.,Bobyleva, A. A.
, p. 1269 - 1276 (2007/10/02)
The iodination and iodochlorination of 3,4-dimethyl-cis-bicyclonona-3,7-diene takes place anomalously.The addition of iodine in carbon tetrachloride leads to the tricyclic monoiodides exo-5-iodo-exo- and exo-5-iodo-endo-1,9-dimethylbrexanes.In pyridine the products from the addition of iodine and pyridine at the least substituted cyclopentene double bond 7-iodo-8-pyridinio-3,4-dimethyl-cis-bicyclonon-3-ene iodides are formed.The addition of iodine chloride in chloroform gives a mixture of the tricyclic monoiodide and the product from addition of iodine and chlorine at the cyclopentene double bond.
