1404616-71-2Relevant academic research and scientific papers
Copper-promoted sulfenylation of sp2 C-H bonds
Tran, Ly Dieu,Popov, Ilya,Daugulis, Olafs
supporting information, p. 18237 - 18240,4 (2020/10/15)
An auxiliary-assisted, copper catalyzed or promoted sulfenylation of benzoic acid derivative β-C-H bonds and benzylamine derivative γ-C-H bonds has been developed. The method employs disulfide reagents, copper(II) acetate, and DMSO solvent at 90-130 °C. Application of this methodology to the direct trifluoromethylsulfenylation of C-H bonds was demonstrated.
