14051-60-6

Basic information

• Product Name: 2β,4,5,6,7,8,8-Heptachloro-4β,7β-methano-3a,4,7,7a-tetrahydroindane
• Synonyms: 2β,4,5,6,7,8,8-Heptachloro-4β,7β-methano-3a,4,7,7a-tetrahydroindane
• CAS NO: 14051-60-6
• Molecular Formula: C10H7Cl7
• Molecular Weight: 375.33358
• Mol File: 14051-60-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2β,4,5,6,7,8,8-Heptachloro-4β,7β-methano-3a,4,7,7a-tetrahydroindane(CAS DataBase Reference)
• NIST Chemistry Reference: 2β,4,5,6,7,8,8-Heptachloro-4β,7β-methano-3a,4,7,7a-tetrahydroindane(14051-60-6)
• EPA Substance Registry System: 2β,4,5,6,7,8,8-Heptachloro-4β,7β-methano-3a,4,7,7a-tetrahydroindane(14051-60-6)

Safety Data

• Hazardous Substances Data: 14051-60-6(Hazardous Substances Data)

Upstream product

• 3734-48-3 chlordene 

Relevant articles and documents

Role of water traces in the liquid-phase catalytic hydrochlorination of olefins in organic solvents

The liquid-phase hydrochlorination of 4,5,6,7,8,8,-hexachloro-3′,4,7,7′-tetrahydro-4,7-methanoindene (Chlordene) catalyzed by gallium or aluminum halides occurs in the presence of water traces in an aprotic organic solvent. Complexes H2O · M2X6, where M is metal and X is halogen, catalyze this reaction. The reaction proceeds under homogeneous conditions. Under heterogeneous catalytic conditions, the solid phase in the AlCl3-CCl4 system attains the required concentration of AlCl3 in the solution. It was shown using quantum-chemical PM3 calculations that the water molecule facilitates the transfer of proton in the form of the hydroxonium ion from an HCl molecule to olefin.