14052-18-7

Basic information

• Product Name: {NiI₂(C₆H₅NH₂)4}
• CAS NO: 14052-18-7
• Molecular Weight: 685.012
• Mol File: 14052-18-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {NiI₂(C₆H₅NH₂)4}(CAS DataBase Reference)
• NIST Chemistry Reference: {NiI₂(C₆H₅NH₂)4}(14052-18-7)
• EPA Substance Registry System: {NiI₂(C₆H₅NH₂)4}(14052-18-7)

Safety Data

• Hazardous Substances Data: 14052-18-7(Hazardous Substances Data)

Upstream product

• 13462-90-3 nickel(II) iodide 
• 62-53-3 aniline 
• 13007-90-4 bis(triphenylphosphine)nickel⁽⁰⁾ dicarbonyl 

Downstream Products

• 13462-90-3 nickel(II) iodide 

Relevant articles and documents

NICKEL-CATALYZED AMIDATION OF BROMO- AND IODOBENZENE

The carbonylation of aryl halides in the presence of p-RC6H4NH2 (R = H, CH3, Cl) or C6H5NHR (R = CH3, C2H5) and a catalytic amount of a nickel(II) or nickel(0) tertiary phosphine complex at 150 degC or above under carbon monoxide pressures is reported.Amides were obtained in high yields in reactions with p-RC6H4NH2, but with C6H5NHR compounds the expected N-alkyl benzanilides were not formed, benzanilide in low yield being formed instead.A possible catalytic cycle based on an active Ni(0)-carbonyl complex is suggested, and the observed deactivation of the catalytic system when the carbon monoxide pressure falls to 6 atm or below, is accounted for in terms of a side reaction which produces an inactive Ni(II) compound.