14056-80-5

Basic information

• Product Name: Rhodium, tribromocarbonylbis(triphenylphosphine)-
• CAS NO: 14056-80-5
• Molecular Formula: C37H30Br3OP2Rh
• Molecular Weight: 895.21
• Mol File: 14056-80-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Rhodium, tribromocarbonylbis(triphenylphosphine)-(CAS DataBase Reference)
• NIST Chemistry Reference: Rhodium, tribromocarbonylbis(triphenylphosphine)-(14056-80-5)
• EPA Substance Registry System: Rhodium, tribromocarbonylbis(triphenylphosphine)-(14056-80-5)

Safety Data

• Hazardous Substances Data: 14056-80-5(Hazardous Substances Data)

Upstream product

• 15318-33-9 chlorocarbonylbis(triphenylphosphine)rhodium(I) 
• 37167-59-2 dimethyl dibromomalonate 

Relevant articles and documents

REACTIONS INVOLVING TRANSITION METALS. XVII. REACTION OF ORGANIC HALOGEN COMPOUNDS WITH 2 AND 2 (S = CH2Cl2, THF)

The complexes 2 and 2 (S=CH2Cl2, THF) have been shown to react with CXCl3 (X=Cl, H) to form with generation of both dichlorocarbene and trichloromethyl radical.Reaction of 2 with CF3I, allyl- and benzyl-halides takes a different course giving organic coupling products and .The THF solvate complex also causes coupling of gem-dihalides, and dehalogenation of vic-dihalides to produce alkenes.Possible mechanisms for these reactions are discussed.