14058-38-9 Usage
Description
Closely allied to the two preceding alkaloids, this base is also obtained from the
leaves of Prosopis africana Taub. It furnishes colourless crystals from Me2CO and
has [el:]D + 25° (CHC13). The structure is 3-hydroxy-6-(11-hydroxydedecyl)-2-
hydroxymethylpiperidine.
References
Khuong-Huu et ai., Bull. Soc. Chim. Belg., 81,425 (972)
Check Digit Verification of cas no
The CAS Registry Mumber 14058-38-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,0,5 and 8 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 14058-38:
(7*1)+(6*4)+(5*0)+(4*5)+(3*8)+(2*3)+(1*8)=89
89 % 10 = 9
So 14058-38-9 is a valid CAS Registry Number.
InChI:InChI=1/C18H37NO3/c1-15(21)10-8-6-4-2-3-5-7-9-11-16-12-13-18(22)17(14-20)19-16/h15-22H,2-14H2,1H3
14058-38-9Relevant articles and documents
A configurational switch based on iridium-catalyzed allylic cyclization: Application in asymmetric total syntheses of prosopis, dendrobate, and spruce alkaloids
Gnamm, Christian,Broedner, Kerstin,Krauter, Caroline M.,Helmchen, Guenter
experimental part, p. 10514 - 10532 (2010/04/29)
A method for the stereoselective synthesis of 2,6-disubstituted piperidines has been developed that is based on the use of an intramolecular iridium-catalyzed allylic substitution as a configurational switch. The procedure allows the preparation of 2-viny
