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Cycloaddition Reaction of Trifluoromethyl Isocyanide to Diphenyl Ethyne
Lentz, Dieter
, p. 148 - 150 (2007/10/02)
The cycloaddition reaction of trifluoromethyl isocyanide to diphenylethyne yields 1,2-diphenyl-3,4-bis(trifluoromethylimino)cyclobutene. 1,2-Diphenyl-3-oxo-4-trifluoromethyliminocyclobutene is obtained as a by-product resulting from hydrolysis.The structure of 1,2-diphenyl-3,4-bis(trifluoromethylimino)cyclobutene has been elucidated by X-ray crystal structure analysis. Key words: Trifluoromethyl isocyanide; cycloaddition reaction; 1,2-diphenyl-3,4-bis(trifluoromethylimino)cyclobutene; crystal structure.
