140705-56-2Relevant academic research and scientific papers
Some novel routes to 1-heterosubstituted 1-vinylcyclopropanes
Lewis, Richard T.,Motherwell, William B.
, p. 1465 - 1484 (2007/10/02)
3-Phenylselenoalk-1-enylidene carbenes, generated in situ by base induced condensation of α-phenylseleno carbonyl compounds and diethyl diazomethylphosphonate, can be efficiently trapped by alkenes to give alkylidene-cyclopropane adducts which undergo either [1,3] allyl selenide rearrangement or oxidative selenoxide [2,3] sigmatropic rearrangement to produce 1-phenylseleno- or 1-hydroxy-1-vinylcyclopropanes respectively.
