1407152-09-3Relevant academic research and scientific papers
A mild method for regioselective de-O-methylation of saccharides by Co2(CO)8/Et3SiH/CO system
Zhao, Yue-tao,Huang, Lu-bai,Li, Qing,Li, Zhong-jun
, p. 5699 - 5706 (2016/08/23)
A new method for cleaving methyl ethers off protected saccharides using Co2(CO)8/Et3SiH/CO system was developed. The method showed regioselectivity in different protected monosaccharides with various anomeric groups. The p
In situ formation of β-glycosyl imidinium triflate from participating thioglycosyl donors: Elaboration to disarmed-armed iterative glycosylation
Lin, Yu Hsien,Ghosh, Bhaswati,Tony Mong, Kwok-Kong
supporting information, p. 10910 - 10912,3 (2020/09/16)
β-Glycosyl imidinium triflate is generated from participating thioglycoside donors for disarmed-armed iterative glycosylations and one-pot oligosaccharide synthesis.
Highly efficient and mild method for regioselective de-O-benzylation of saccharides by Co2(CO)8-Et3SiH-CO reagent system
Yin, Zhao-Jun,Wang, Bo,Li, Yang-Bing,Meng, Xiang-Bao,Li, Zhong-Jun
supporting information; experimental part, p. 536 - 539 (2010/05/02)
[Chemical equation presented] A highly efficient and mild method for the de-O-benzylation of protected saccharides was developed by transforming terminal benzyl ethers Into silyl ethers using Co2(CO)8-Et 3SIH under 1 atm of CO. The method was successfully used for the de-O-benzylatlon of perbenzylated monosaccharides with various anomerlc protecting groups, as well as natural disaccharldes and trisaccharides such as sucrose, raffinose, and melezltose In good yields (>80%).
