1407186-24-6Relevant academic research and scientific papers
Asymmetric β-boration of α,β-unsaturated N -acyloxazolidinones by [2.2]paracyclophane-based bifunctional catalyst
Zhao, Lei,Ma, Yudao,Duan, Wenzeng,He, Fuyan,Chen, Jianqiang,Song, Chun
supporting information, p. 5780 - 5783 (2013/01/15)
An efficient copper-catalyzed asymmetric conjugate boration has been achieved by exploiting a new planar and central chiral bicyclic triazolium ligand. This protocol was highly efficient and gave a variety of chiral secondary alkylboronates in 97-99% ee. A preliminary mechanistic study supports the bifunctional nature of the catalyst.
