14074-63-6Relevant articles and documents
Method for preparing biphenyldianhydride through microwave-assisted catalytic coupling
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Paragraph 0027-0028; 0033-0034; 0036-0037, (2021/11/06)
The invention discloses a method for preparing biphenyldianhydride through microwave-assisted catalytic coupling. In a green solvent 2 - methyltetrahydrofuran (2-THF) system, under microwave irradiation, under microwave irradiation, under a temperature 60 - 95 °C condition, the reaction time is over 20-60 minutes to prepare a biphenyl derivative, and after hydrolysis and dehydration, biphenyldianhydride is obtained. The present invention is characterized in that an organometallic complex is formed by using a halogenated monomer having a complexing action, and zinc halide generated by the reaction with the reaction. It is avoided that its deposition on the reducing agent metal surface results in a reduction in its reducing ability. Compared with the traditional method for preparing the same biphenyl dianhydride, the method is high in reaction speed, the reducing agent is close to the quantitative reaction, and the cost is lower.
Grinding imidation of anhydrides on smectite clays as recyclable and heterogeneous catalysts under solvent-free conditions
Marvi, Omid
, p. 3501 - 3504 (2017/08/14)
Imidation of various anhydrides employing solvent-free grindstone technique using smectite clays as recyclable and green catalysts was examined and obtained excellent yields.
Rapid and convenient microwave-assisted synthesis of aromatic imides and N-hydroxymethylimides
Kacprzak, Karol
, p. 1499 - 1507 (2007/10/03)
Extremely simple high-yielding and rapid microwave-assisted synthesis of wide array of aromatic mono and diimides and mono- and bis-N-hydroxymethylimides is reported.