1407495-77-5

Basic information

• Product Name: bis[3,5-bis(4-methoxyphenyl)-1H-pyrrol-2-yl-3,5-bis(4-methoxyphenyl)-2-ylideneamine]cobalt(II)
• Synonyms: bis[3,5-bis(4-methoxyphenyl)-1H-pyrrol-2-yl-3,5-bis(4-methoxyphenyl)-2-ylideneamine]cobalt(II)
• CAS NO: 1407495-77-5
• Molecular Weight: 1196.3
• Mol File: 1407495-77-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis[3,5-bis(4-methoxyphenyl)-1H-pyrrol-2-yl-3,5-bis(4-methoxyphenyl)-2-ylideneamine]cobalt(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bis[3,5-bis(4-methoxyphenyl)-1H-pyrrol-2-yl-3,5-bis(4-methoxyphenyl)-2-ylideneamine]cobalt(II)(1407495-77-5)
• EPA Substance Registry System: bis[3,5-bis(4-methoxyphenyl)-1H-pyrrol-2-yl-3,5-bis(4-methoxyphenyl)-2-ylideneamine]cobalt(II)(1407495-77-5)

Safety Data

• Hazardous Substances Data: 1407495-77-5(Hazardous Substances Data)

Upstream product

• 873975-75-8 [3,5-bis(4-methoxyphenyl)-1H-pyrrol-2-yl]-[3,5-bis(4-methoxyphenyl)pyrrol-2-ylidene]amine 
• 6147-53-1 cobalt(II) diacetate tetrahydrate 

Relevant articles and documents

Azadipyrromethene dye derivatives in coordination chemistry: The structure-property relationship in homoleptic metal(II) complexes

As a chromophore closely related to dipyrromethene (DPM), the azadipyrromethene (ADPM) family has attracted much interest in the life sciences and optoelectronic fields. A high-yielding microwave-assisted synthesis is reported for new homoleptic complexes of cobalt(II), nickel(II), copper(II) and zinc(II) based on the tetrakis(p-methoxyphenyl)azadipyrromethene ligand 1b. These complexes are compared with other homoleptic complexes of the same metal(II) series based on the tetraphenylazadipyrromethene 1a and also with related BF2+ chelates (Aza-BODIPYs 6a and 6b) for a better understanding of trends arising from substitution of the chelate and/or the electron-donating effect of the p-methoxy substituents. The electrochemical behavior of the new compounds 2b, 3b, and 5b in dichloromethane revealed two pseudoreversible reductions (2b, -1.09 and -1.25 V vs SCE; 3b, -1.05 and -1.29 V; 5b, -1.13 and -1.25 V) followed by a third irreversible process (2b, -1.78 V; 3b, -1.80 V; 5b, -1.77 V) along with two pseudoreversible oxidations (2b, 0.55 and 0.80 V; 3b, 0.56 and 0.80 V; 5b, 0.55 and 0.80 V) followed by two closely spaced irreversible processes (2b, 1.21 and 1.27 V; 3b, 1.21 and 1.28 V; 5b, 1.22 and 1.25 V). On its side, copper(II) homoleptic complex 4b revealed only one pseudoreversible reduction at -0.59 V followed by three irreversible processes at -0.95, -1.54, and -1.74 V, respectively. The oxidation behavior of this complex exhibited two pseudoreversible processes (0.55 and 0.82 V) and two irreversible processes (1.19 and 1.25 V). The redox processes are assigned and discussed in relation to their photophysical properties. X-ray structures for 1b and related copper(II) complex 2b are also discussed.