14078-59-2Relevant academic research and scientific papers
Substituent effects in the oxidation of 2-alkyl-1,4-dialkoxybenzenes with ceric ammonium nitrate
Love, Brian E.,Simmons, Alexander L.
, p. 5712 - 5715 (2016/11/29)
Increased steric size of alkyl groups and the presence of coordinating atoms on alkoxy groups have both been found to contribute to decreasing yields of diquinones upon reaction of 2-alkyl-1,4-dialkoxybenzenes with CAN. The overall hydrophilicity of the substrates does not appear to be a significant factor in determining the diquinone yield for these reactions.
Effects of reaction conditions on quinone/diquinone product ratios in the oxidation of 1,4-dimethoxybenzene derivatives with ceric ammonium nitrate
Love, Brian E.,Duffy, Brian C.,Simmons, Alexander L.
supporting information, p. 1994 - 1997 (2014/04/03)
Proper choice of reaction conditions allows formation of either the quinone or corresponding diquinone as the major product upon treatment of 2-alkyl-1,4-dimethoxybenzenes with ceric ammonium nitrate.
Improved synthesis of diquinones
Love, Brian E.,Bonner-Stewart, Jeffrey,Forrest, Lori A.
body text, p. 813 - 817 (2009/06/19)
Preparation of a series of substituted diquinones is reported. In most examples, inverse order of addition (addition of a dimethoxybenzene derivative to a CAN solution) has been found to produce higher yields of diquinones than the traditional protocol in which the oxidant is added to the arene. Georg Thieme Verlag Stuttgart.
