1408191-56-9Relevant academic research and scientific papers
Formation of thiosemicarbazone-functionalized complexes with (GeS 2)2 and (SnS2)2 units
Eussner, Jens P.,Dehnen, Stefanie
, p. 1827 - 1832 (2012)
By reaction of organo-functionalized germanium or tin sesquisulfides [(R1T)4S6] (T = Ge, Sn; R1 = CMe2CH2COMe) with thiosemicarbazide or its methyl or phenyl derivative, a series of four compounds were obtained and structurally characterized that are based on an inorganic (TS2)2 unit with an extended organic chelate ligand CMe2CH 2CMeNNCSNHR′ (R′ = H, Me, Ph). The products combine a small, reactive metal chalcogenide moiety with a ligand system that allows for a variety of directed extensions at the terminal NHR′ group. Thus, this work represents the starting point to a multifaceted consecutive chemistry involving both the extension of the binary inorganic unit and further derivatization and/or coordination of the organic ligands. Copyright
