140836-83-5

Upstream product

• 4784-77-4 (E)-1-Bromo-2-butene 
• 2746-25-0 p-Methoxybenzyl bromide 
• 17417-82-2 1-Methyl-2-propenyl phenyl selenide 
• 824-94-2 p-methoxybenzyl chloride 
• 16599-72-7 crotyl phenyl selenide 

Relevant academic research and scientific papers

Regioselective cross-coupling of allylindium reagents with activated benzylic bromides-a simple and efficient procedure for the synthesis of terminal alkenes

Allylindium reagents undergo facile and highly regioselective cross-coupling with benzylic and cinnamyl bromides in THF at room temperature without any catalyst producing terminal alkenes in high yields. The addition is highly regioselective and is found to provide γ-adducts in all reactions.

A facile synthesis of 1,5-dienes by a regioselective allylation of the allylic arbanions generated from allyl phenyl selenides

Allyl-allyl or benzyl coupling reactions were effected by allyl carbanions, generated from allyl phenyl selenides and n-butyllithium, and allylic or benzylic halides. The ambident selectivities of the allyl carbanions are depending on the solvent system.