140839-07-2

Basic information

• Product Name: [1,3]Azaphospholo[1,2-a]pyridine-3-carbonitrile, 2-(1,1-dimethylethyl)-7-methyl-
• CAS NO: 140839-07-2
• Molecular Formula: C13H15N2P
• Molecular Weight: 230.249
• Mol File: 140839-07-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1,3]Azaphospholo[1,2-a]pyridine-3-carbonitrile, 2-(1,1-dimethylethyl)-7-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: [1,3]Azaphospholo[1,2-a]pyridine-3-carbonitrile, 2-(1,1-dimethylethyl)-7-methyl-(140839-07-2)
• EPA Substance Registry System: [1,3]Azaphospholo[1,2-a]pyridine-3-carbonitrile, 2-(1,1-dimethylethyl)-7-methyl-(140839-07-2)

Safety Data

• Hazardous Substances Data: 140839-07-2(Hazardous Substances Data)

Upstream product

• 78129-68-7 2,2-dimethylpropylidynephosphine 
• 3189-57-9 4-methylpyridinium dicyanomethylide 

Relevant articles and documents

A new access to phosphaindolizines by [3+2] cycloaddition of azomethine ylides onto phosphaalkynes

Azomethine ylides such as 1 and 4 in which the nitrogen atom is incorporated in a six-membered heterocyclic ring undergo regiospecific [3+2] cycloadditions with the phosphaalkynes 2a and b at 130-140 °C to furnish the phosphaindolizines 3 and 5a-c after elimination of ethyl formate or hydrogen cyanide, respectively. In contrast, dipoles of the type 6 react unspecifically with the phosphaalkyne 2a to yield the regioisomers 7 and 8.