140849-70-3

Upstream product

• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 
• 917-54-4 methyllithium 
• 1822-00-0 trimethylsilylmethyllithium 
• 140658-50-0 (2R,3R,4S,5R,6R)-3,4,5-tris-benzyl-6-benzyloxymethyl-2-dichloromethyltetrahydro-2H-pyran-2-ol 
• 138811-41-3 ((3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-2-hydroxy-tetrahydro-pyran-2-yl)-acetic acid ethyl ester 
• 138760-57-3 3,4,5,7-Tetra-O-benzyl-1-deoxy-1-C-trimethylsilyl-D-gluco-2-heptulopyranose 
• 133697-34-4 2,6-anhydro-3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-hept-1-enitol 
• 131603-38-8 (5R,6R,7S,8R)-6,7,8-Tris-benzyloxy-5-benzyloxymethyl-1,4-dioxa-spiro[2.5]octane 

Downstream Products

• 95189-55-2 3,4,5,7-Tetra-O-benzyl-2,6-anhydro-1-deoxy-D-glycero-D-gulo-heptitol 

Relevant academic research and scientific papers

Stereoselective C-allylation of 1-C-alkyl-2,3,4,6-tetra-O-benzyl-D-glucopyranoses with allyltrimethylsilane

The reaction of 1-C-alkyl-2,3,4,6-tetra-O-benzyl-D-glucopyanoses with allyltrimethylsilane in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulfonate gave the corresponding C-allylated C-alkyl glucopyranosides in good yields. This C

Studies on the synthesis of C-glycoside sulfones as potential glycosyl transferase inhibitors

β-C-Glycoside sulfoxides and sulfones were prepared by radical addition of thiol acetic acid to exocyclic glycals followed by deacetylation, S-alkylation, and selective oxidation. These compounds are representative examples of a new class of molecules designed to be glycosyl transferase inhibitors.

Reaction of pyranoid and furanoid aldonolactones with chloromethyltrimethylsilane-derived reagents

Reaction of pyranoid and furanoid aldonolactones with trimethylsilylmethyl-lithium provides a convenient route to carbon-chain-elongated methyl ketones. Reaction of the lactones with chloro(trimethylsilyl)methyl-lithium gives the corresponding chloromethylketones. Reaction of pyranoid and furanoid aldonolactones with trimethylsilylmethyl-lithium provides a convenient route to carbon-chain-elongated methyl ketones. Reaction of the lactones with chloro(trimethylsilyl)methyl-lithium gives the corresponding chloromethylketones.