140849-70-3Relevant articles and documents
Stereoselective C-allylation of 1-C-alkyl-2,3,4,6-tetra-O-benzyl-D-glucopyranoses with allyltrimethylsilane
Yamanoi, Takashi,Oda, Yoshiki
, p. 229 - 234 (2007/10/03)
The reaction of 1-C-alkyl-2,3,4,6-tetra-O-benzyl-D-glucopyanoses with allyltrimethylsilane in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulfonate gave the corresponding C-allylated C-alkyl glucopyranosides in good yields. This C
Studies on the synthesis of C-glycoside sulfones as potential glycosyl transferase inhibitors
Gervay, Jacquelyn,Flaherty, Terrence M.,Holmes, Daniel
, p. 16355 - 16364 (2007/10/03)
β-C-Glycoside sulfoxides and sulfones were prepared by radical addition of thiol acetic acid to exocyclic glycals followed by deacetylation, S-alkylation, and selective oxidation. These compounds are representative examples of a new class of molecules designed to be glycosyl transferase inhibitors.
Reaction of pyranoid and furanoid aldonolactones with chloromethyltrimethylsilane-derived reagents
Glanzer,Csuk
, p. 79 - 92 (2007/10/02)
Reaction of pyranoid and furanoid aldonolactones with trimethylsilylmethyl-lithium provides a convenient route to carbon-chain-elongated methyl ketones. Reaction of the lactones with chloro(trimethylsilyl)methyl-lithium gives the corresponding chloromethylketones. Reaction of pyranoid and furanoid aldonolactones with trimethylsilylmethyl-lithium provides a convenient route to carbon-chain-elongated methyl ketones. Reaction of the lactones with chloro(trimethylsilyl)methyl-lithium gives the corresponding chloromethylketones.