14090-31-4Relevant articles and documents
Phenyltetrafluorotelluromethoxide - A new fluorinating reagent for olefins
Lermontov,Bahtin
, p. 722 - 723 (1998)
Phenyltetrafluorotelluromethoxide fluorinates olefins to form 1,2-difluorides. The reaction with styrene afforded 1-fluoro-4-phenyl-1,2-dihydronaphthalene as the main product.
A clean and selective radical homocoupling employing carboxylic acids with titania photoredox catalysis
Manley, David W.,Walton, John C.
supporting information, p. 5394 - 5397 (2015/02/19)
A titania photoredox catalysis protocol was developed for the homocoupling of C-centered radicals derived from carboxylic acids. Intermolecular reactions were generally efficient and selective, furnishing the desired dimers in good yields under mild neutral conditions. Selective cross-coupling with two acids proved unsuccessful. An intra-molecular adaptation enabled macrocycles to be prepared, albeit in modest yields. (Chemical Equation Presented).
Utility of silicon tetrafluoride as a catalyst of reactions with xenon difluoride: Fluorinations of phenyl alkenes and benzaldehydes
Tamura, Masanori,Takagi, Toshiyuki,Quan, Heng-Dao,Sekiya, Akira
, p. 163 - 166 (2007/10/03)
Application of silicon tetrafluoride to fluorinations with xenon difluoride as a catalyst is investigated. It was found that vic-difluorination of phenyl alkenes and transformation of benzaldehydes to difluoromethoxybenzenes using xenon difluoride are enhanced by silicon tetrafluoride.