140901-91-3Relevant academic research and scientific papers
A Novel Entry into Wittig Rearrangements - A Stereoselective -Wittig Rearrangement with Inversion of Configuration at the Carbanion Center
Hoffmann, Rolf,Brueckner, Reinhard
, p. 1957 - 1964 (2007/10/02)
The O,Se ketal 10, through lithium naphthalenide induced reductive cleavage of its Csp3-Se bond, was converted into the α-lithio ether 11a with an equatorially oriented C-O bond.At -78 deg C, 11a undergoes a rapid -Wittig rearra
