140928-67-2Relevant academic research and scientific papers
Highly Stereoselective 3 + 2 Annulations by Cyclopropanation of Vinyl Ethers with Rhodium(II)-Stabilized Vinylcarbenoids Followed by a Formally Forbidden 1,3-Sigmatropic Rearrangement
Davies, Huw M. L.,Hu, Baihua
, p. 3186 - 3190 (2007/10/02)
A highly stereoselective 3 + 2 annulation has been developed by cyclopropanation of vinyl ethers with rhodium(II)-stabilized vinylcarbenoids to generate vinylcyclopropanes followed by a Et2AlCl-catalyzed 1,3-sigmatropic rearrangement.The success of this m
