14094-11-2

Usage

Uses

Used in Organic Synthesis:
TERT-BUTYL METHYL SULFOXIDE is used as a solvent for chemical reactions due to its high polarity and stability, facilitating various organic synthesis processes.
Used in Oxidation Reactions:
TERT-BUTYL METHYL SULFOXIDE is used as a reagent for the oxidation of organic compounds, enabling selective and efficient oxidation processes in organic chemistry.
Used in Biological Research:
TERT-BUTYL METHYL SULFOXIDE is used as a cryoprotectant for biological samples, helping to preserve the integrity of samples during freezing and storage.
Used in Lithium Battery Industry:
TERT-BUTYL METHYL SULFOXIDE is used as a co-solvent in lithium batteries, contributing to improved battery performance and safety.
Used in Metal Surface Protection:
TERT-BUTYL METHYL SULFOXIDE is used as a corrosion inhibitor for metal surfaces, providing protection against corrosion and extending the lifespan of metal components.
It is important to handle TERT-BUTYL METHYL SULFOXIDE with caution, as it can cause skin and eye irritation, and may be harmful if ingested or inhaled.

InChI:InChI=1/C5H12OS/c1-5(2,3)7(4)6/h1-4H3

Upstream product

• 6163-64-0 tert-butyl methyl sulphide 
• 52693-45-5 Methylsulfinsaeure-n-propylester 
• 677-22-5 tert-butylmagnesium chloride 
• 74-88-4 methyl iodide 
• 31401-20-4 O-Neopentyl-methansulfinat 

Downstream Products

• 4345-98-6 2,2,6,6-tetramethyl-3,5-dithiaheptane 
• 16185-03-8 2-tert-Butylthiomethyl-6-methyl-phenol 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 25432-20-6 tert-butyl ethyl sulfoxide 
• 63017-95-8 N-Methyl-N,2-diphenyl-2-(methylthio)acetamid 
• 1323993-85-6 (+/-)-2-[(tert-butylsulfinyl)methyl]chroman-2-ol 
• 1323993-99-2 C₁₄H₂₀O₃S 

Relevant academic research and scientific papers

Photocatalytic water-soluble cationic platinum(II) complexes bearing quinolinate and phosphine ligands

Cationic Pt(II) complexes ([Pt(QO/S)(PΛP)]X), having 8-oxy or 8-thioquinolinate (QO/S) and seven different mono- or bidentate phosphines as ligands, have been synthesized and characterized. The photophysical, stability, and photocatalytic properties of th

Sodium hypochlorite-promoted novel synthesis of organic ammonium tribromides and application of phenanthroline hydrotribromide in chemoselective oxidation of organic sulfides by hydrogen peroxide

A novel method of synthesis of organic ammonium tribromides (OATBs) is developed by using an inexpensive and eco-friendly sodium hypochlorite as oxidant for conversion of Br to Br3 . The OATBs thus prepared include both quaternary ammonium tribromides and N-heterocyclic tribromides. A new addition to the family of OATBs is made in the form of phenanthroline hydrotribromide. The efficacy of this new tribromide as catalyst is ascertained in the oxidative transformation of organic sulfides to their corresponding sulfoxides and sulfones by hydrogen peroxide.

Alloxazine-cyclodextrin conjugates for organocatalytic enantioselective sulfoxidations

Four structurally different alloxazine-cyclodextrin conjugates were prepared and tested as catalysts for the enantioselective oxidation of prochiral sulfides to sulfoxides by hydrogen peroxide in aqueous solutions. The alloxazinium unit was appended to the primary face of α- and β-cyclodextrins via a linker with variable length. A series of sulfides was used as substrates: n-alkyl methyl sulfides (n-alkyl = hexyl, octyl, decyl, dodecyl), cyclohexyl methyl sulfide, tert-butyl methyl sulfide, benzyl methyl sulfide and thioanisol. α-Cyclodextrin conjugate having alloxazinium unit attached via a short linker proved to be a suitable catalyst for oxidations of n-alkyl methyl sulfides, displaying conversions up to 98% and enantioselectivities up to 77% ee. β-Cyclodextrin conjugates were optimal catalysts for the oxidation of sulfides carrying bulkier substituents; e.g. tert-butyl methyl sulfide was oxidized with quantitative conversion and 91% ee. Low loadings (0.3-5 mol%) of the catalysts were used. No overoxidation to sulfones was observed in this study.

Mild, Selective, and Efficient Oxidation of Sulfides to Sulfoxides Catalyzed by Mn(III)-Salen Complexes

A detailed optimization of the catalytic environment for the oxidation of sulfides promoted by Mn(salen)/H2O2 systems is proposed. The experimental setup is demonstrated to be active towards different substrates, providing TOFs up to 9300 h-1, which are among the highest reported for homogeneous catalysts employed in sulfoxidation reactions.

A nickel nanoparticle engineered CoFe2O4/SiO2-NH2@carboxamide composite as a novel scaffold for the oxidation of sulfides and oxidative coupling of thiols

The purpose of this work was to prepare a new Ni-carboxamide complex supported on CoFe2O4 nanoparticles (CoFe2O4/SiO2-NH2@carboxamide-Ni). The carboxamide host material unit generated cavities that stabilized the nickel nanoparticles effectively and preve

Luminescent cis-Bis(bipyridyl)ruthenium(II) Complexes with 1,2-Azolylamidino Ligands: Photophysical, Electrochemical Studies, and Photocatalytic Oxidation of Thioethers

New 1,2-azolylamidino complexes cis-[Ru(bipy)2(NH=C(R)az*-κ2N,N)](OTf)2 (R = Me, Ph; az? = pz, indz, dmpz) are synthesized via chloride abstraction after a subsequent base-catalyzed coupling of a nitrile with the previously coordinated 1,2-azole. The synt

Chemoselective α-sulfidation of amides using sulfoxide reagents

The direct α-sulfidation of tertiary amides using sulfoxide reagents under electrophilic amide activation conditions is described. Employing convenient and readily available reagents, selective functionalization takes place to generate isolable sulfonium

Imine-Based Covalent Organic Frameworks as Photocatalysts for Metal Free Oxidation Processes under Visible Light Conditions

Photochemistry of extended polyimine COF structures with laminar, spherical and 3D architectures has been examined. We show that these materials, composed by undecorated phenyl rings and imine fragments, can act as photocatalyts in oxidative transformatio

Bovine serum albumin-cobalt(II) Schiff base complex hybrid: An efficient artificial metalloenzyme for enantioselective sulfoxidation using hydrogen peroxide

An artificial metalloenzyme (BSA-CoL) based on the incorporation of a cobalt(ii) Schiff base complex {CoL, H2L = 2,2′-[(1,2-ethanediyl)bis(nitrilopropylidyne)]bisphenol} with bovine serum albumin (BSA) has been synthesized and characterized. Attention is focused on the catalytic activity of this artificial metalloenzyme for enantioselective oxidation of a variety of sulfides with H2O2. The influences of parameters such as pH, temperature, and the concentration of catalyst and oxidant on thioanisole as a model are investigated. Under optimum conditions, BSA-CoL as a hybrid biocatalyst is efficient for the enantioselective oxidation of a series of sulfides, producing the corresponding sulfoxides with excellent conversion (up to 100%), chemoselectivity (up to 100%) and good enantiomeric purity (up to 87% ee) in certain cases.

Pt(II) coordination complexes as visible light photocatalysts for the oxidation of sulfides using batch and flow processes

A new catalytic system for the photooxidation of sulfides based on Pt(ii) complexes is presented. The catalyst is capable of oxidizing a large number of sulfides containing aryl, alkyl, allyl, benzyl, as well as more complex structures such as heterocycles and methionine amino acid, with complete chemoselectivity. In addition, the first sulfur oxidation in a continuous flow process has been developed.