141023-04-3Relevant articles and documents
Chemoselective Trifluoromethylation of Methyl Esters Using an Et3GeNa/C6H5SCF3 Combination: Efficient Synthesis of Trifluoromethyl Ketones
Yokoyama, Yasuo,Mochida, Kunio
, p. 907 - 908 (1997)
Various trifluoromethyl ketones were synthesized from the corresponding methyl esters by effective nucleophilic trifluoromethylation using an Et3GeNa/C6H5SCF3 combination. This trifluoromethylation proceeded che
A new entry for the oxidation of fluoroalkyl-substituted methanol derivatives: Scope and limitation of the organoiodine(V) reagent-catalyzed oxidation
Tanaka, Yusuke,Ishihara, Takashi,Konno, Tsutomu
experimental part, p. 99 - 104 (2012/05/07)
Oxidation of various fluoroalkyl-substituted methanol derivatives under the influence of a catalytic amount of sodium 2-iodobenzenesulfonate and Oxone in CH3CN or CH3NO2 was investigated in detail. The efficiency of the newly developed oxidation was also evaluated by comparison to other oxidations, such as Dess-Martin, PDC, and Swern oxidation.
An expedient access to trifluoromethyl ketones from carboxylic acids
Boivin, Jean,El Kaim, Laurent,Zard, Samir Z.
, p. 1285 - 1288 (2007/10/02)
Trifluoromethyl ketones are prepared in good yield from carboxylic acid chlorides by reaction with pyridine and trifluoroacetic anhydride.