141076-94-0

Basic information

• Product Name: (Z)-(2S,3R,7S)-1,7-Bis-benzyloxy-2-methyl-oct-5-en-3-ol
• Synonyms: (Z)-(2S,3R,7S)-1,7-Bis-benzyloxy-2-methyl-oct-5-en-3-ol
• CAS NO: 141076-94-0
• Molecular Weight: 354.489
• Mol File: 141076-94-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-(2S,3R,7S)-1,7-Bis-benzyloxy-2-methyl-oct-5-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-(2S,3R,7S)-1,7-Bis-benzyloxy-2-methyl-oct-5-en-3-ol(141076-94-0)
• EPA Substance Registry System: (Z)-(2S,3R,7S)-1,7-Bis-benzyloxy-2-methyl-oct-5-en-3-ol(141076-94-0)

Safety Data

• Hazardous Substances Data: 141076-94-0(Hazardous Substances Data)

Upstream product

• 79027-28-4 (2S)-3-(benzyloxy)-2-methylpropanal 
• 119204-58-9 (4S,2E)-4-Phenylmethoxypent-2-enyl(tributyl)stannane 

Relevant articles and documents

Effective 1,5-asymmetric induction in tin(IV) chloride promoted reactions between aldehydes and (4-alkoxy-2-alkenyl)tributylstannanes

Transmetallation of (S)-4-benzyloxy-2-pentenyl(tributyl)stannane (1) using tin(IV) chloride generates an allyltin trichloride which reacts in situ with aldehydes to give 1-substituted syn-(3Z)-5-benzyloxyhexenols with excellent stereoselectivity. With chiral aldehydes, the stereoselectivity of the reaction is dominated by the reagent, except for 2-alkoxyaldehydes which show matching and mismatching consistent with preferred Felkin-Anh diastereofacial selectivity.