141076-96-2Relevant academic research and scientific papers
Effective 1,5-asymmetric induction in tin(IV) chloride promoted reactions between aldehydes and (4-alkoxy-2-alkenyl)tributylstannanes
McNeill,Thomas
, p. 322 - 334 (2007/10/02)
Transmetallation of (S)-4-benzyloxy-2-pentenyl(tributyl)stannane (1) using tin(IV) chloride generates an allyltin trichloride which reacts in situ with aldehydes to give 1-substituted syn-(3Z)-5-benzyloxyhexenols with excellent stereoselectivity. With chiral aldehydes, the stereoselectivity of the reaction is dominated by the reagent, except for 2-alkoxyaldehydes which show matching and mismatching consistent with preferred Felkin-Anh diastereofacial selectivity.
1,5-Asymmetric induction in reactions of δ-alkoxyallylstannanes: Stereoselective reactions with chiral aldehydes
McNeill, Alan H.,Thomas, Eric J.
, p. 1369 - 1372 (2007/10/02)
Transmetallation of (4S,2E)-4-phenylmethoxypent-2-enyl(tributyl)stannane 1 using tin(IV)chloride generates a reagent which shows excellent 1 5-stereoselectivity in reactions with aldehydes: with chiral aldehydes, the stereochemical preference of the reage
