141077-45-4Relevant academic research and scientific papers
Redox mediators of hydrogen sulfide oxidation in reactions with cycloalkanes
Berberova,Shinkar',Smolyaninov,Pashchenko
, p. 295 - 298 (2015)
An indirect electrochemical method for thiolation of cycloalkanes C5-C7 has been suggested. The method is based on a new approach to activation of hydrogen sulfide by redox mediators.
Iron catalysed insertion of sulfur into the non-activated C-H bond
Balavoine,Barton,Gref,Lellouche
, p. 1883 - 1894 (2007/10/02)
The reaction of various sulfur reagents (S8, H2S, Na2S, NaHS) with cyclohexane under Gif(III), GoAgg(II) and GoAgg(III) conditions affords the usual oxidation products in competition with cyclohexyl di- and poly-sulfide formation. Other cyclic hydrocarbons behave similarly. The sulfation reactions are considered to be biomimetic for the enzymes isopenicillin N synthase and biotin synthase.
