1411704-46-5Relevant articles and documents
Unexpected conversion of alkyl azides to alkyl iodides and of aryl azides to N-tert-butyl anilines
Maury, Julien,Feray, Laurence,Bertrand, Michele P.,Kapat, Ajoy,Renaud, Philippe
, p. 9606 - 9611,6 (2012)
In the presence of tert-butyl iodide, alkyl azides are converted into the corresponding iodides at room temperature, whereas, N-t-Bu anilines are obtained from aryl azides under the same experimental conditions. A mechanism is proposed to explain this unusual reactivity.