141216-58-2Relevant academic research and scientific papers
Synthesis and reactivity of ruthenatetraboranes: Molecular structure of [RuH(B3H8)(CO)(PPh3)2]
Alcock, Nathaniel W.,Burns, Ian D.,Claire, Kanwaljit S.,Hill, Anthony F.
, p. 4606 - 4610 (2008/10/08)
The reactions of [RuClH(CO)(PPh3)3] and [RuH(CO)(NCMe)2(PPh3)2]ClO4 with [NMe4][B3H8] provide the ruthenatetraborane [RuH(B3H8)(CO)(PPh3)2] [crystallographically characterized: monoclinic crystals of space group P21/c (Z = 4), in a unit cell of dimensions a = 14.424 (5) ?, b = 10.628 (4) ?, c = 22.987 (9) ?, and β = 97.86 (3)°]. The integrity of the RuB3 moiety is retained in the reactions with N-halosuccinimides, leading to the halo derivatives [RuX(B3H8) (CO) (PPh3)2] (X = Cl, Br, I); however, reaction of the bromo derivative with Na[S2CNMe2] leads to rupture of the-metallatetraborane and formation of [Ru(S2CNMe2)2(CO)(PPh3)].
Synthesis and reactivity of hydrido, halogeno, and ?-organyl ruthenatetraboranes: Crystal structure of
Burns, Ian D.,Hill, Anthony F.,Thompsett, Andrew R.,Alcock, Nathaniel W.,Claire, Kanwaljit S.
, p. C8 - C10 (2007/10/02)
The reaction of (n = 2, R = ?-vinyl, ?-aryl; n = 3, R = H) with NMe4 provide the ruthenatetraboranes .The crystal structure was determined for the compound with R = H.The latter reacts with N-halogeno succini
